Sky are allowing Neville - who was previously part of the England coaching set-up under Roy Hodgson - to work for ITV in Russia.
ITV will share coverage of the tournament with the BBC, and have so far nabbed the opening match between Russia and Saudi Arabia on June 14 along with England's opening group game against Belgium.
Matches will air on ITV and ITV4 with Mark Pougatch ITV's main anchor with Neville joining ITV's regular pundits Ryan Giggs, Roy Keane, Ian Wright and Lee Dixon.
ITV's coverage will be presented from a studio overlooking St Basil's Cathedral in Red Square in Moscow.
The BBC has also revealed its World Cup team - details HERE
***WHO'S SHOWING WHICH GAMES - BREAKDOWN OF BBC & ITV'S LIVE WORLD CUP GAMES IN THE GROUP STAGES HERE***
ITV SPORT'S WORLD CUP 2018 SQUAD
Presenters: Mark Pougatch & Jacqui Oatley
Pundits and experts: Gary Neville, Ryan Giggs, Ian Wright, Lee Dixon, Eniola Aluko, Patrice Evra, Henrik Larson, Martin O' Neil, Slaven Bilic, Mark Clattenburg.
Commentators: Clive Tyldesley, Sam Matterface, Jon Champion, Joe Speight
Co-commentators: Glenn Hoddle, Ally McCoist, Iain Dowie.
Reporters: Gabriel Clare, Seema Jaswal.